cd /home/daytona/workspace && python3 -c " import pdfplumber pdf_path = '/home/daytona/workspace/attachments/5edc402f-5e2e-48e1-ac20-ac9bb1737105/past papers 2015-25 🌚🤍.pdf' with pdfplumber.open(pdf_path) as pdf: print(f'Total pages: {len(pdf.pages)}') for i, page in enumerate(pdf.pages[:5]): print(f'--- PAGE {i+1} ---') text = page.extract_text() if text: print(text[:2000]) else: print('[No text extracted]') "

cd /home/daytona/workspace && python3 -c " import pdfplumber pdf_path = '/home/daytona/workspace/attachments/5edc402f-5e2e-48e1-ac20-ac9bb1737105/past papers 2015-25 🌚🤍.pdf' with pdfplumber.open(pdf_path) as pdf: for i, page in enumerate(pdf.pages[5:]): print(f'--- PAGE {i+6} ---') text = page.extract_text() if text: print(text[:3000]) else: print('[No text extracted]') "

python3 -c "from PIL import Image, ImageDraw, ImageFont; print('Pillow available')"

python3 << 'PYEOF' from PIL import Image, ImageDraw, ImageFont import os # A4 dimensions at 150 DPI W, H = 1240, 1754 img = Image.new('RGB', (W, H), color='white') draw = ImageDraw.Draw(img) # Try to load fonts def get_font(size, bold=False): paths = [ f'/usr/share/fonts/truetype/dejavu/DejaVuSans{"Bold" if bold else ""}.ttf', f'/usr/share/fonts/truetype/liberation/LiberationSans-{"Bold" if bold else "Regular"}.ttf', '/usr/share/fonts/truetype/dejavu/DejaVuSans.ttf', ] for p in paths: if os.path.exists(p): return ImageFont.truetype(p, size) return ImageFont.load_default() font_title = get_font(22, bold=True) font_sub = get_font(17, bold=True) font_normal = get_font(15) font_bold = get_font(15, bold=True) font_small = get_font(13) font_large = get_font(18, bold=True) margin_l = 60 margin_r = W - 60 y = 30 def line(draw, y, x1=60, x2=None): if x2 is None: x2 = W - 60 draw.line([(x1, y), (x2, y)], fill='black', width=2) return y + 4 def text_c(draw, txt, y, font, color='black'): bbox = draw.textbbox((0, 0), txt, font=font) tw = bbox[2] - bbox[0] draw.text(((W - tw) // 2, y), txt, fill=color, font=font) return y + (bbox[3] - bbox[1]) + 6 def text_l(draw, txt, y, font, x=60, color='black', wrap_width=1120): # Simple word wrap words = txt.split() current_line = '' lines_out = [] for word in words: test = current_line + (' ' if current_line else '') + word bbox = draw.textbbox((0, 0), test, font=font) if bbox[2] - bbox[0] > wrap_width and current_line: lines_out.append(current_line) current_line = word else: current_line = test if current_line: lines_out.append(current_line) for l in lines_out: draw.text((x, y), l, fill=color, font=font) bbox = draw.textbbox((0, 0), l, font=font) y += (bbox[3] - bbox[1]) + 5 return y # ─── HEADER ──────────────────────────────────────────────────────────── y = line(draw, y + 2) y = text_c(draw, 'UNIVERSITY OF THE PUNJAB, LAHORE', y + 4, font_title) y = text_c(draw, 'FACULTY OF PHARMACY', y + 2, font_sub) y = line(draw, y + 4) y = text_c(draw, 'ANNUAL EXAMINATION 2026', y + 4, font_sub) y = text_c(draw, 'B. Pharm Part-I | PHARMACEUTICAL CHEMISTRY – I', y + 2, font_sub) y = text_c(draw, '(ORGANIC CHEMISTRY) – THEORY', y + 2, font_large) y = line(draw, y + 6) # Time / Marks row draw.text((margin_l, y + 4), 'Time Allowed: 3 Hours', font=font_bold, fill='black') bbox = draw.textbbox((0,0), 'Total Marks: 80', font=font_bold) draw.text((W - margin_l - (bbox[2]-bbox[0]), y + 4), 'Total Marks: 80', font=font_bold, fill='black') y += 28 y = line(draw, y) # Instructions y = text_c(draw, 'GUESS PAPER 2026 (Based on Past Papers 2015–2025)', y + 6, font_bold, color='#880000') y += 4 instructions = [ 'Note: Attempt Q.No.2 (Compulsory) and any FOUR questions from the remaining.', 'Q.No.2 carries 20 marks (5 short questions × 4 marks each).', 'Each remaining question carries 20 marks (Part a = 10, Part b = 10).', 'Use of calculator is NOT allowed. Write clearly and legibly.', ] for ins in instructions: y = text_l(draw, ins, y, font_small, x=margin_l) y += 4 y = line(draw, y) # ─── Q2 COMPULSORY ───────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.2', font=font_bold, fill='black') draw.text((margin_l + 50, y), '(COMPULSORY) Write short notes on ANY FIVE of the following: (5 × 4 = 20)', font=font_bold, fill='black') y += 26 short_qs = [ '(i) Define Inductive Effect and give its applications in organic chemistry.', '(ii) Explain Hydrogen Bonding with examples.', '(iii) Define Optical Isomerism. What is a chiral centre?', '(iv) Differentiate between Carbocation, Carbanion, and Free Radical.', '(v) Explain R and S System of Configuration (CIP rules).', '(vi) Define Resonance and state conditions for resonance.', '(vii) What is Hyperconjugation? Give its effects on stability.', '(viii) Define Aromaticity and state Hückel\'s Rule with examples.', '(ix) Write a note on Hemolytic and Heterolytic Fission.', '(x) Define Carbene and Nitrene with examples.', ] for q in short_qs: y = text_l(draw, q, y, font_normal, x=margin_l + 50, wrap_width=1060) y += 2 y += 4 y = line(draw, y) # ─── Q3 ────────────────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.3', font=font_bold, fill='black') bbox = draw.textbbox((0,0), '(20 Marks)', font=font_bold) draw.text((W - margin_l - bbox[2], y), '(20 Marks)', font=font_bold, fill='black') y += 24 y = text_l(draw, '(a) Define and explain Resonance. Describe rules for drawing resonance structures with suitable examples.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 4 y = text_l(draw, '(b) Write a comprehensive note on Conformational Analysis of ethane and butane. Draw Newman projections and energy diagrams.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 6 y = line(draw, y) # ─── Q4 ────────────────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.4', font=font_bold, fill='black') bbox = draw.textbbox((0,0), '(20 Marks)', font=font_bold) draw.text((W - margin_l - bbox[2], y), '(20 Marks)', font=font_bold, fill='black') y += 24 y = text_l(draw, '(a) Describe in detail the methods of preparation, chemical reactions, tests for identification, and pharmaceutical applications of Alcohols.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 4 y = text_l(draw, '(b) Describe the methods of preparation, chemical properties, tests for identification, and pharmaceutical applications of Phenols.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 6 y = line(draw, y) # ─── Q5 ────────────────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.5', font=font_bold, fill='black') bbox = draw.textbbox((0,0), '(20 Marks)', font=font_bold) draw.text((W - margin_l - bbox[2], y), '(20 Marks)', font=font_bold, fill='black') y += 24 y = text_l(draw, '(a) Discuss in detail Nucleophilic Substitution Reactions (SN1 and SN2). Give mechanisms, examples, and factors affecting these reactions.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 4 y = text_l(draw, '(b) Describe the Electrophilic Substitution Reactions of Benzene (Halogenation, Nitration, Sulphonation, Friedel-Crafts Alkylation and Acylation) with mechanisms.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 6 y = line(draw, y) # ─── Q6 ────────────────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.6', font=font_bold, fill='black') bbox = draw.textbbox((0,0), '(20 Marks)', font=font_bold) draw.text((W - margin_l - bbox[2], y), '(20 Marks)', font=font_bold, fill='black') y += 24 y = text_l(draw, '(a) Write a detailed note on Heterocyclic Compounds. Describe methods of preparation, properties, and pharmaceutical applications of Pyrrole and Pyridine.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 4 y = text_l(draw, '(b) Describe methods of preparation and chemical reactions of Quinoline and Indole. Give their pharmaceutical importance.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 6 y = line(draw, y) # ─── Q7 ────────────────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.7', font=font_bold, fill='black') bbox = draw.textbbox((0,0), '(20 Marks)', font=font_bold) draw.text((W - margin_l - bbox[2], y), '(20 Marks)', font=font_bold, fill='black') y += 24 y = text_l(draw, '(a) How is Grignard Reagent prepared? Describe its applications in the synthesis of primary, secondary, and tertiary alcohols, and carboxylic acids.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 4 y = text_l(draw, '(b) Explain the following reaction mechanisms: (i) Baeyer-Villiger Oxidation (ii) Diels-Alder Reaction. Give applications of each.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 6 y = line(draw, y) # ─── Q8 ────────────────────────────────────────────────────────────── y += 8 draw.text((margin_l, y), 'Q.8', font=font_bold, fill='black') bbox = draw.textbbox((0,0), '(20 Marks)', font=font_bold) draw.text((W - margin_l - bbox[2], y), '(20 Marks)', font=font_bold, fill='black') y += 24 y = text_l(draw, '(a) Explain Pinacol-Pinacolone Rearrangement with mechanism and applications. Also briefly describe Hoffmann Rearrangement.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 4 y = text_l(draw, '(b) Describe the mechanism and applications of: (i) Aldol Condensation (ii) Mannich Reaction.', y, font_normal, x=margin_l + 10, wrap_width=1100) y += 6 y = line(draw, y) # ─── FOOTER ────────────────────────────────────────────────────────── y += 10 y = text_c(draw, '*** Good Luck ***', y, font_bold, color='#880000') y += 4 y = text_c(draw, 'Guess Paper prepared from Past Papers (2015–2025) | Punjab University Lahore – Annual Exam 2026', y, font_small, color='#555555') y = line(draw, y + 6) # Save os.makedirs('/home/daytona/workspace/guess-paper', exist_ok=True) out_path = '/home/daytona/workspace/guess-paper/PU_Organic_Chemistry_Guess_Paper_2026.png' img.save(out_path, dpi=(150, 150)) print(f'Saved to {out_path}') print(f'Image size: {img.size}') PYEOF

python3 << 'PYEOF' from PIL import Image, ImageDraw, ImageFont import os # A4 dimensions at 150 DPI - we'll trim later W = 1240 img_full = Image.new('RGB', (W, 2200), color='white') draw = ImageDraw.Draw(img_full) def get_font(size, bold=False): paths = [ f'/usr/share/fonts/truetype/liberation/LiberationSans-{"Bold" if bold else "Regular"}.ttf', f'/usr/share/fonts/truetype/dejavu/DejaVuSans{"Bold" if bold else ""}.ttf', '/usr/share/fonts/truetype/dejavu/DejaVuSans.ttf', ] for p in paths: if os.path.exists(p): return ImageFont.truetype(p, size) return ImageFont.load_default() font_title = get_font(24, bold=True) font_sub = get_font(18, bold=True) font_normal = get_font(15) font_bold = get_font(15, bold=True) font_small = get_font(13) font_large = get_font(20, bold=True) font_q = get_font(16, bold=True) ML = 65 # margin left MR = W - 65 # margin right CW = MR - ML # content width # Draw outer double border draw.rectangle([10, 10, W-10, 2190], outline='black', width=3) draw.rectangle([16, 16, W-16, 2184], outline='black', width=1) y = 28 def hline(y, x1=ML-5, x2=None, width=1): if x2 is None: x2 = MR+5 draw.line([(x1, y), (x2, y)], fill='black', width=width) return y + 4 def text_c(txt, y, font, color='black'): bbox = draw.textbbox((0, 0), txt, font=font) tw = bbox[2] - bbox[0] th = bbox[3] - bbox[1] draw.text(((W - tw) // 2, y), txt, fill=color, font=font) return y + th + 7 def text_l(txt, y, font, x=ML, color='black', indent=0): x2 = x + indent wrap = MR - x2 - 5 words = txt.split() current = '' lines_out = [] for w in words: test = current + (' ' if current else '') + w bb = draw.textbbox((0,0), test, font=font) if (bb[2]-bb[0]) > wrap and current: lines_out.append(current) current = w else: current = test if current: lines_out.append(current) for l in lines_out: draw.text((x2, y), l, fill=color, font=font) bb = draw.textbbox((0,0), l, font=font) y += (bb[3]-bb[1]) + 5 return y def text_r(txt, y, font, color='black'): bb = draw.textbbox((0,0), txt, font=font) draw.text((MR - (bb[2]-bb[0]), y), txt, fill=color, font=font) # ═══ HEADER ═════════════════════════════════════════════════ y = text_c('UNIVERSITY OF THE PUNJAB, LAHORE', y, font_title) y = text_c('College of Pharmacy', y - 2, font_sub) y = hline(y + 2, width=2) y = text_c('ANNUAL EXAMINATION – 2026', y + 4, font_sub) y = text_c('B. Pharm Part – I', y - 2, font_sub) y = hline(y + 4, width=1) y = text_c('PHARMACEUTICAL CHEMISTRY – I (ORGANIC CHEMISTRY)', y + 6, font_large) y = text_c('( T H E O R Y )', y - 2, font_sub) y = hline(y + 6, width=2) # Time / Marks draw.text((ML, y + 5), 'Time Allowed: 3 Hours', font=font_bold, fill='black') text_r('Maximum Marks: 80', y + 5, font_bold) y += 26 y = hline(y + 2, width=2) # Red Guess Paper banner draw.rectangle([ML-5, y+4, MR+5, y+28], fill='#880000') bb = draw.textbbox((0,0), 'GUESS PAPER 2026 ● Based on Past Papers 2015–2025 ● Punjab University Lahore', font=font_bold) tw = bb[2] - bb[0] draw.text(((W-tw)//2, y+7), 'GUESS PAPER 2026 ● Based on Past Papers 2015–2025 ● Punjab University Lahore', fill='white', font=font_bold) y += 36 y = hline(y + 2, width=1) # Instructions box draw.rectangle([ML-5, y+4, MR+5, y+82], fill='#f8f8f8', outline='black', width=1) y += 8 y = text_l('NOTE:', y, font_bold, x=ML+5) y = text_l('1. Attempt Q.No. 2 which is COMPULSORY and any FOUR questions from Q.3 to Q.8.', y-3, font_small, x=ML+10) y = text_l('2. Q.No. 2 consists of 5 short questions, each carrying 4 marks (Total: 5 × 4 = 20 Marks).', y, font_small, x=ML+10) y = text_l('3. Each of the remaining questions carries 20 marks, divided into Part (a) and Part (b), 10 marks each.', y, font_small, x=ML+10) y = text_l('4. Do not write anything on the question paper except your Roll No.', y, font_small, x=ML+10) y += 4 y = hline(y + 2, width=2) # ═══ Q.2 COMPULSORY ══════════════════════════════════════════ y += 8 draw.rectangle([ML-5, y-2, MR+5, y+22], fill='#003366', outline='black', width=1) draw.text((ML+5, y+2), 'Q.2 (COMPULSORY) Write short notes on ANY FIVE of the following: [5 × 4 = 20 Marks]', fill='white', font=font_q) y += 30 short_qs = [ '(i) Define Inductive Effect. Explain its types (+I and –I effects) with pharmaceutical applications.', '(ii) Explain Hydrogen Bonding. Discuss its effects on boiling point and solubility.', '(iii) Define Optical Isomerism. What is a chiral centre? Give examples of optically active compounds.', '(iv) Differentiate between Carbocation, Carbanion, and Free Radical with examples.', '(v) Explain R and S System of Configuration (CIP priority rules) with examples.', '(vi) Define Resonance. State conditions and rules for drawing resonance structures.', '(vii) What is Hyperconjugation? Describe its effects on stability of alkenes and carbocations.', '(viii) Define Aromaticity and state Hückel\'s Rule. Identify aromatic, anti-aromatic compounds.', '(ix) Define Hemolytic and Heterolytic Bond Fission. Give one example of each.', '(x) Define Carbene and Nitrene. Describe their types and reactivity.', ] for q in short_qs: y = text_l(q, y, font_normal, x=ML+12) y += 3 y += 4 y = hline(y, width=2) # ═══ Q.3 ═════════════════════════════════════════════════════ def question_header(q_num, y): draw.rectangle([ML-5, y, MR+5, y+22], fill='#e8e8e8', outline='black', width=1) draw.text((ML+5, y+3), f'Q.{q_num}', fill='black', font=font_q) text_r('(20 Marks)', y+4, font_bold) return y + 28 y = question_header(3, y+4) y = text_l('(a) Define and explain Resonance. Describe the rules for drawing resonance structures. Illustrate with suitable examples from pharmaceutical molecules. [10]', y, font_normal, x=ML+10) y += 6 y = text_l('(b) Write a comprehensive note on Conformational Analysis of ethane and n-butane. Draw Newman projections of all conformers and energy diagrams showing relative stability. [10]', y, font_normal, x=ML+10) y += 4 y = hline(y+4, width=2) # ═══ Q.4 ═════════════════════════════════════════════════════ y = question_header(4, y+4) y = text_l('(a) Describe in detail the methods of preparation, chemical reactions, tests for identification, and pharmaceutical applications of Monohydric Alcohols. [10]', y, font_normal, x=ML+10) y += 6 y = text_l('(b) Describe the methods of preparation, chemical properties, tests for identification, and pharmaceutical importance of Phenols. Give reactions of phenol with FeCl₃ and Bromine water. [10]', y, font_normal, x=ML+10) y += 4 y = hline(y+4, width=2) # ═══ Q.5 ═════════════════════════════════════════════════════ y = question_header(5, y+4) y = text_l('(a) Discuss in detail the Nucleophilic Substitution Reactions – SN1 and SN2. Describe their mechanisms, stereochemistry, examples, and factors affecting each. [10]', y, font_normal, x=ML+10) y += 6 y = text_l('(b) Describe Electrophilic Substitution Reactions of Benzene: Halogenation, Nitration, Sulphonation, Friedel-Crafts Alkylation, and Friedel-Crafts Acylation. Give mechanisms. [10]', y, font_normal, x=ML+10) y += 4 y = hline(y+4, width=2) # ═══ Q.6 ═════════════════════════════════════════════════════ y = question_header(6, y+4) y = text_l('(a) Define and classify Heterocyclic Compounds. Describe the methods of preparation, chemical properties, electrophilic substitution reactions, and pharmaceutical applications of Pyrrole and Pyridine. [10]', y, font_normal, x=ML+10) y += 6 y = text_l('(b) Describe the methods of preparation and important chemical reactions of Quinoline and Indole. Discuss their pharmaceutical significance. [10]', y, font_normal, x=ML+10) y += 4 y = hline(y+4, width=2) # ═══ Q.7 ═════════════════════════════════════════════════════ y = question_header(7, y+4) y = text_l('(a) How is Grignard Reagent prepared? Describe its applications in the synthesis of primary, secondary, and tertiary alcohols, aldehydes, ketones, and carboxylic acids. [10]', y, font_normal, x=ML+10) y += 6 y = text_l('(b) Explain the following named reactions giving general equations, mechanisms, and applications: (i) Baeyer-Villiger Oxidation (ii) Diels-Alder Reaction. [10]', y, font_normal, x=ML+10) y += 4 y = hline(y+4, width=2) # ═══ Q.8 ═════════════════════════════════════════════════════ y = question_header(8, y+4) y = text_l('(a) Explain the Pinacol-Pinacolone Rearrangement with complete mechanism, driving force, and applications. Also describe Hoffmann Rearrangement briefly. [10]', y, font_normal, x=ML+10) y += 6 y = text_l('(b) Describe the mechanism and applications of: (i) Aldol Condensation (ii) Mannich Reaction. Write general equations for each. [10]', y, font_normal, x=ML+10) y += 4 y = hline(y+4, width=2) # ═══ FOOTER ═══════════════════════════════════════════════════ y += 10 draw.rectangle([ML-5, y, MR+5, y+24], fill='#003366', outline='black', width=1) bb = draw.textbbox((0,0), '*** Best of Luck to All Students ***', font=font_bold) draw.text(((W-(bb[2]-bb[0]))//2, y+4), '*** Best of Luck to All Students ***', fill='white', font=font_bold) y += 32 y = text_c('Guess Paper compiled from PUCP Past Papers 2015–2025 | Annual Exam 2026 | Pharmaceutical Chemistry-I (Organic Chemistry)', y, font_small, color='#444444') y += 4 y = hline(y, width=2) # Crop to content final_h = y + 20 img_cropped = img_full.crop((0, 0, W, final_h)) # Resize outer border to match img_final = Image.new('RGB', (W, final_h), color='white') img_final.paste(img_cropped) d2 = ImageDraw.Draw(img_final) d2.rectangle([10, 10, W-10, final_h-10], outline='black', width=3) d2.rectangle([16, 16, W-16, final_h-16], outline='black', width=1) out_path = '/home/daytona/workspace/guess-paper/PU_Organic_Chemistry_Guess_Paper_2026.png' img_final.save(out_path, dpi=(150, 150)) print(f'Saved: {out_path}') print(f'Size: {img_final.size}') PYEOF