A new headache plus repeated jerking of only the left hand needs emergency assessment now. Call your local emergency number or go to an emergency department immediately. Do not drive yourself.
One-sided involuntary hand jerks can be a focal motor seizure, which may arise from the right side of the brain, but with a new or unusual headache clinicians also need to urgently exclude causes such as stroke, bleeding, infection, or another brain problem. Focal myoclonus can be an epileptic manifestation. Localization in Clinical Neurology, 8e, lines 5556-5559.
Call emergency services now especially if there is any weakness or numbness, face droop, speech or vision change, confusion, loss of awareness, fever or stiff neck, vomiting, severe sudden onset, or a recent head injury.
Until seen: stay with someone, sit or lie somewhere safe, avoid alcohol or recreational drugs, and note when the jerks began, how long they last, and whether awareness changes.