cheistry mock for neet 2026

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Here's your NEET 2026 Chemistry Mock Test — 50 questions, full syllabus, mixed difficulty. Each question is single correct answer (4 options), just like the real NEET.

🧪 NEET 2026 — Chemistry Mock Test

Total Questions: 50 | Marks: +4 / –1 | Time Suggested: 60 minutes

SECTION A — Physical Chemistry (Q1–18)


Q1. The unit of rate constant for a second-order reaction is:
  • A) mol L⁻¹ s⁻¹
  • B) s⁻¹
  • C) L mol⁻¹ s⁻¹
  • D) L² mol⁻² s⁻¹

Q2. For a reaction A → B, the rate doubles when concentration of A is doubled. The order of reaction is:
  • A) Zero
  • B) First
  • C) Second
  • D) Third

Q3. At 300 K, the activation energy of a reaction is 83.14 kJ/mol. By how many times does the rate increase if temperature is raised from 300 K to 310 K? (R = 8.314 J mol⁻¹ K⁻¹)
  • A) 2.37
  • B) 3.04
  • C) 1.89
  • D) 4.12

Q4. The entropy change for melting of 1 mol of ice at 273 K is approximately: (ΔH_fus = 6.02 kJ/mol)
  • A) 22.05 J K⁻¹ mol⁻¹
  • B) 18.6 J K⁻¹ mol⁻¹
  • C) 6.02 J K⁻¹ mol⁻¹
  • D) 273 J K⁻¹ mol⁻¹

Q5. Which of the following solutions has the highest boiling point?
  • A) 0.1 M glucose
  • B) 0.1 M NaCl
  • C) 0.1 M BaCl₂
  • D) 0.1 M AlCl₃

Q6. van't Hoff factor (i) for K₂SO₄ at complete dissociation is:
  • A) 1
  • B) 2
  • C) 3
  • D) 4

Q7. Henry's law constant (KH) for a gas increases with temperature. What does this imply?
  • A) Solubility of gas increases with temperature
  • B) Solubility of gas decreases with temperature
  • C) Solubility is independent of temperature
  • D) KH is independent of the gas

Q8. For the cell: Zn | Zn²⁺ (1M) || Cu²⁺ (1M) | Cu, E°cell = 1.10 V. What is ΔG° for this cell reaction? (F = 96500 C/mol)
  • A) –212.3 kJ/mol
  • B) –106.15 kJ/mol
  • C) +212.3 kJ/mol
  • D) –424.6 kJ/mol

Q9. Which plot gives a straight line for a first-order reaction?
  • A) [A] vs t
  • B) 1/[A] vs t
  • C) ln[A] vs t
  • D) 1/[A]² vs t

Q10. What is the pH of a buffer containing 0.1 M CH₃COOH and 0.1 M CH₃COONa? (pKa = 4.74)
  • A) 4.74
  • B) 3.74
  • C) 5.74
  • D) 7.00

Q11. The wavelength of light emitted when an electron in hydrogen falls from n=3 to n=2 is approximately:
  • A) 656 nm
  • B) 486 nm
  • C) 434 nm
  • D) 410 nm

Q12. Which of the following has maximum lattice energy?
  • A) NaF
  • B) NaCl
  • C) MgO
  • D) CaO

Q13. Osmotic pressure of a 0.01 M glucose solution at 27°C is: (R = 0.083 L·bar mol⁻¹K⁻¹)
  • A) 0.249 bar
  • B) 2.49 bar
  • C) 24.9 bar
  • D) 0.0249 bar

Q14. For adsorption, which combination is always true at equilibrium?
  • A) ΔH > 0, ΔS > 0
  • B) ΔH < 0, ΔS < 0
  • C) ΔH > 0, ΔS < 0
  • D) ΔH < 0, ΔS > 0

Q15. The number of atoms in 1 g of ⁵⁶Fe is: (NA = 6.022 × 10²³)
  • A) 6.022 × 10²³
  • B) 1.075 × 10²²
  • C) 3.35 × 10²¹
  • D) 6.022 × 10²¹

Q16. Which gas deviates most from ideal behaviour at high pressure?
  • A) H₂
  • B) N₂
  • C) CO₂
  • D) He

Q17. Equivalent conductance of a solution increases on dilution because:
  • A) Ions move faster
  • B) Degree of dissociation increases
  • C) Viscosity increases
  • D) Number of ions decreases

Q18. In Freundlich adsorption isotherm, a plot of log(x/m) vs log P gives a straight line with slope:
  • A) n
  • B) 1/n
  • C) log k
  • D) k

SECTION B — Organic Chemistry (Q19–36)


Q19. Which reagent converts a primary alcohol to an aldehyde without over-oxidation?
  • A) KMnO₄ / H⁺
  • B) K₂Cr₂O₇ / H₂SO₄
  • C) PCC (Pyridinium chlorochromate)
  • D) CrO₃

Q20. The IUPAC name of CH₃–CH(OH)–COOH is:
  • A) 2-Hydroxybutanoic acid
  • B) 2-Hydroxypropanoic acid
  • C) 3-Hydroxypropanoic acid
  • D) 2-Methylpropanoic acid

Q21. Which of the following is an electrophile?
  • A) NH₃
  • B) BF₃
  • C) OH⁻
  • D) :CH₂

Q22. The major product of the reaction of 1-butene with HBr in the presence of peroxide is:
  • A) 2-Bromobutane
  • B) 1-Bromobutane
  • C) 1,2-Dibromobutane
  • D) 2-Methylbutane

Q23. Which compound shows geometrical isomerism?
  • A) CH₂=CH₂
  • B) CHCl=CHCl
  • C) CH₂=CCl₂
  • D) CH₃–CH₃

Q24. Lucas test is used to distinguish:
  • A) Primary, secondary, and tertiary alcohols
  • B) Aldehydes and ketones
  • C) Amines and amides
  • D) Alkenes and alkynes

Q25. The reaction of benzene with Cl₂ in the presence of FeCl₃ proceeds via:
  • A) Free radical mechanism
  • B) Electrophilic addition
  • C) Electrophilic substitution
  • D) Nucleophilic substitution

Q26. Aniline reacts with CH₃COCl to form:
  • A) N-Methylaniline
  • B) Acetanilide
  • C) Benzamide
  • D) Phenyl isocyanate

Q27. Fehling's solution is reduced by:
  • A) Glucose only
  • B) Fructose only
  • C) Both glucose and fructose
  • D) Sucrose

Q28. Which of the following amino acids has a non-polar R-group?
  • A) Serine
  • B) Aspartic acid
  • C) Glycine
  • D) Lysine

Q29. The degree of unsaturation (DBE) of C₆H₅–NH₂ (aniline) is:
  • A) 3
  • B) 4
  • C) 5
  • D) 6

Q30. Chlorobenzene is less reactive toward nucleophilic substitution than chloroalkanes because:
  • A) C–Cl bond is stronger in chlorobenzene due to resonance
  • B) Benzene ring is electron-rich
  • C) Both A and B
  • D) Cl is a better leaving group in chloroalkanes

Q31. The polymer formed by condensation of hexamethylene diamine and adipic acid is:
  • A) Nylon-6
  • B) Nylon-6,6
  • C) Dacron
  • D) Bakelite

Q32. Identify the reducing sugar among the following:
  • A) Sucrose
  • B) Maltose
  • C) Starch
  • D) Cellulose

Q33. The reaction of an aldehyde with excess methanol in the presence of dry HCl gives:
  • A) Hemiacetal
  • B) Acetal
  • C) Ester
  • D) Ether

Q34. Which of the following undergoes Cannizzaro reaction?
  • A) CH₃CHO
  • B) HCHO
  • C) CH₃COCH₃
  • D) C₆H₅COCH₃

Q35. The number of sigma (σ) bonds in benzene (C₆H₆) is:
  • A) 6
  • B) 9
  • C) 12
  • D) 15

Q36. Which test is specific for proteins?
  • A) Tollens' test
  • B) Biuret test
  • C) Benedict's test
  • D) Ninhydrin test (for amino acids only)

SECTION C — Inorganic Chemistry (Q37–50)


Q37. Which of the following oxides is amphoteric?
  • A) Na₂O
  • B) SO₃
  • C) Al₂O₃
  • D) CaO

Q38. The correct order of ionic radii is:
  • A) Na⁺ > Mg²⁺ > Al³⁺
  • B) Al³⁺ > Mg²⁺ > Na⁺
  • C) Mg²⁺ > Na⁺ > Al³⁺
  • D) Na⁺ > Al³⁺ > Mg²⁺

Q39. In the extraction of copper, the final step is:
  • A) Calcination
  • B) Smelting
  • C) Bessemerisation
  • D) Electrolytic refining

Q40. Which of the following transition metals has the highest oxidation state?
  • A) Mn
  • B) Cr
  • C) Fe
  • D) Cu

Q41. The geometry of [Ni(CN)₄]²⁻ is:
  • A) Tetrahedral
  • B) Square planar
  • C) Octahedral
  • D) Trigonal planar

Q42. Which of the following compounds exhibits linkage isomerism?
  • A) [Co(en)₂Cl₂]⁺
  • B) [Co(NO₂)(NH₃)₅]²⁺
  • C) [Cr(H₂O)₆]³⁺
  • D) [CoCl₂(NH₃)₄]⁺

Q43. The hybridization of PCl₅ is:
  • A) sp³
  • B) sp³d
  • C) sp³d²
  • D) dsp²

Q44. Which of the following halogens has the highest electron gain enthalpy (most negative)?
  • A) F
  • B) Cl
  • C) Br
  • D) I

Q45. The shape of XeF₄ is:
  • A) Tetrahedral
  • B) See-saw
  • C) Square planar
  • D) Trigonal bipyramidal

Q46. In the contact process for manufacture of H₂SO₄, SO₃ is absorbed in:
  • A) Water directly
  • B) Dilute H₂SO₄
  • C) Concentrated H₂SO₄ (oleum process)
  • D) NaOH solution

Q47. Which of the following has the highest first ionization energy?
  • A) Na
  • B) Mg
  • C) Al
  • D) Si

Q48. The CFSE (Crystal Field Stabilization Energy) is maximum for which configuration in a strong field octahedral complex?
  • A) d⁴
  • B) d⁶
  • C) d³
  • D) d⁸

Q49. Which of the following is not a characteristic of transition metals?
  • A) Variable oxidation states
  • B) Formation of coloured ions
  • C) Diamagnetic behaviour in all compounds
  • D) Catalytic activity

Q50. The ore of aluminium is:
  • A) Galena
  • B) Chalcopyrite
  • C) Bauxite
  • D) Magnetite

✅ Answer Key

QAnsQAnsQAnsQAnsQAns
1C11A21B31B41B
2B12C22B32B42B
3B13A23B33B43B
4A14B24A34B44B
5D15B25C35C45C
6C16C26B36B46C
7B17B27C37C47B
8A18B28C38A48B
9C19C29B39D49C
10A20B30C40A50C

📝 Quick Explanations for Tricky Questions

Q3: Use Arrhenius: k₂/k₁ = e^[Ea/R × (1/T₁ – 1/T₂)] = e^[(83140/8.314)(1/300 – 1/310)] ≈ 3.04
Q4: ΔS = ΔH/T = 6020/273 = 22.05 J K⁻¹ mol⁻¹
Q5: AlCl₃ → 4 ions (van't Hoff factor = 4), so highest colligative effect → highest boiling point
Q8: ΔG° = –nFE° = –2 × 96500 × 1.10 = –212,300 J = –212.3 kJ/mol
Q13: π = CRT = 0.01 × 0.083 × 300 = 0.249 bar
Q22: Peroxide effect → Anti-Markovnikov → Br adds to terminal carbon → 1-bromobutane
Q29: DBE of C₆H₇N = (2×6 + 2 – 7 + 1)/2 = (12+2–7+1)/2 = 8/2 = 4
Q35: Benzene: 6 C–H σ bonds + 6 C–C σ bonds = 12 σ bonds
Q48: d⁶ in strong octahedral field → configuration t₂g⁶ eg⁰ → CFSE = –2.4Δo → maximum

Scoring:
  • 45–50 correct → Excellent (AIR top 1000 range)
  • 35–44 → Good (NIT/state medical ready)
  • 25–34 → Average (needs focused revision)
  • Below 25 → Revisit NCERT fundamentals
Good luck for NEET 2026! 🎯
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